4-Chloro-N-(4-chlorophenyl)-2-methylbenzenesulfonamide
نویسندگان
چکیده
In the title compound, C(13)H(11)Cl(2)NO(2)S, the conformations of the N-C bonds in the C-SO(2)-NH-C segment have gauche torsions with respect to the S=O bonds. Further, the conformation of the N-H bond is syn to the ortho-methyl group in the sulfonyl benzene ring. The torsion angle of the C-SO(2)-NH-C segment in the mol-ecule is 55.0 (2)°. The two benzene rings are tilted relative to each other by 67.0 (1)°. In the crystal, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into infinite column-like chains.
منابع مشابه
N-(3-Chlorophenyl)-4-methylbenzenesulfonamide
In the title compound, C(13)H(12)ClNO(2)S, the conformation of the N-H bond is anti to the 3-chloro group in the aniline benzene ring. The dihedral angle between the two benzene rings is 73.7 (1)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O hydrogen bonds.
متن کامل4-Chloro-N-(2-chlorophenyl)-2-methylbenzenesulfonamide
In the crystal structure of the title compound, C(13)H(11)Cl(2)NO(2)S, the conformations of the N-C bond in the C-SO(2)-NH-C segment are trans and gauche with respect to the S=O bonds. The C-S(O(2))-N(H)-C torsion angle is 74.8 (4)°, indicating that the mol-ecule is bent at the S atom. In the crystal structure, inversion dimers linked by pairs of N-H⋯O hydrogen bonds occur. An intramolecular N-...
متن کامل4-Chloro-N-(3-chlorophenyl)-2-methylbenzenesulfonamide
In the title compound, C(13)H(11)Cl(2)NO(2)S, the conformation of the N-H bond in the C-SO(2)-NH-C segment is anti to the meta-Cl atom on the aniline ring and syn to the ortho-methyl group on the sulfonyl-benzene ring. Furthermore, the torsion angle of the C-SO(2)-NH-C segment in the mol-ecule is 80.1 (3)°. The two benzene rings are tilted relative to each other by 70.9 (1)°. In the crystal, pa...
متن کاملN-(2-Chlorophenyl)-4-methylbenzenesulfonamide
The mol-ecule of the title compound, C(13)H(12)ClNO(2)S, is bent at the S atom with a C-SO(2)-NH-C torsion angle of -54.8 (2)°. The dihedral angle between the two aromatic rings is 71.6 (1)°. An intra-molecular N-H⋯Cl hydrogen bond is observed. The crystal structure features inversion-related dimers formed by pairs of N-H⋯O hydrogen bonds.
متن کامل{2-[(1,3-Benzothiazol-2-yl)methoxy]-5-chlorophenyl}(4-chlorophenyl)methanone
In the title compound, C21H13Cl2NO2S, the benzo-thia-zole ring makes dihedral angles of 0.94 (1) and 70.65 (5)° with the 4-chloro-phenyl-methanone unit and the 5-chloro-phenyl ring, respectively. The dihedral angle between the 4-chloro-phenyl-methanone unit and the 5-chloro-phenyl ring is 66.20 (5)°. The crystal structure consists of dimeric units generated by C-H⋯N hydrogen bonds, further link...
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